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Sunday, September 23, 2012

BORN-HABER CYCLE

The Born-Haber cycle is an approach to analyzing reaction energies. It was developed by Max Born and Fritz Haber. This cycle is used as a means of calculating lattice energies which cannot be measured directly. The Born-Haber cycle applies Hess's Law to calculate the lattice enthalpy by comparing the standart enthalpy change of formation of the ionic compound (from the elements) to the enthalpy required to make gaseous ions from the elements.
For example is Formation of Metal Chloride: 

Figure 1. Hess's Law of Metal Chloride, MCl formation

From the Hess's Law the lattice enthalpy formation of MCl, (delta)Hf , can be calculated as:




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